%mem=7700MB
%nproc=4
%nosave
%chk=pyrZM.chk
#P b3lyp/lanl2dz Opt=(CalcAll,VTight) SCF=(Tight) Pop=(Regular) nosymm Int=UltraFine Density=Current 
geom=(PrintInputOrien,AllCheck)  Freq=Raman

pyrZM

0 1
 N
 C                  1              B1
 C                  1              B2    2              A1
 C                  1              B3    3              A2    2              D1
 C                  3              B4    1              A3    4              D2
 C                  4              B5    1              A4    3              D3
 H                  2              B6    6              A5    4              D4
 H                  3              B7    1              A6    4              D5
 H                  4              B8    1              A7    3              D6
 H                  5              B9    3              A8    1              D7
 H                  6             B10    4              A9    1              D8

   B1             2.82860983
   B2             1.36201710
   B3             1.36650745
   B4             1.41586763
   B5             1.41879705
   B6             1.08633524
   B7             1.08707623
   B8             1.08780386
   B9             1.08494510
   B10            1.08510581
   A1            59.22875882
   A2           118.44443182
   A3           122.40979239
   A4           122.34165424
   A5           120.49436294
   A6           116.30338407
   A7           116.36279312
   A8           119.88255866
   A9           119.97866780
   D1             0.00297024
   D2             0.01111859
   D3            -0.00480837
   D4          -179.98460764
   D5          -179.99696052
   D6          -179.99130704
   D7           180.00000000
   D8          -179.99489866

 1 3 1.5 4 1.5
 2 5 1.5 6 1.5 7 1.0
 3 5 1.5 8 1.0
 4 6 1.5 9 1.0
 5 10 1.0
 6 11 1.0
 7
 8
 9
 10