%mem=7700MB
%nproc=4
%nosave
%chk=pyrRdFreq.chk
#P b3lyp/lanl2dz Opt Pop=Regular nosymm 
Density=Current geom=PrintInputOrien Freq=Raman CPHF=RdFreq

pyr

0 1
 N  0               -0.01057900   -0.00063900   -2.28646300
 C  0               -1.17676700   -0.00590200   -2.99007400
 C  0                1.16741700    0.00509200   -2.97902000
 C  0               -1.20903000   -0.00586700   -4.40557400
 H  0               -2.09264300   -0.01032000   -2.40450900
 C  0                1.21421300    0.00563000   -4.39704500
 H  0                2.07779200    0.00903900   -2.38360500
 C  0                0.00585100    0.00014800   -5.11502500
 H  0               -2.16179300   -0.01018900   -4.92454400
 H  0                2.17150600    0.01019200   -4.90795000
 H  0                0.01008200    0.00016100   -6.20135200

 295nm 325nm 370nm 514nm 630nm 785nm