%mem=7700MB
%nproc=4
%nosave
%chk=Cu10pyrZ00.chk
#p b3lyp/lanl2dz Opt=(VTight) SCF=Tight Geom=AllCheck Guess=TCheck Pop=Regular nosymm Int=UltraFine Density=Current 

--link1--
%chk=Cu10pyrZ00.chk
#p b3lyp/lanl2dz SCF=Tight Geom=AllCheck Guess=TCheck Freq=NNRaman CPHF=RdFreq Pop=Regular nosymm Int=UltraFine Density=Current

--link1--
%chk=Cu10pyrZ00.chk
#p b3lyp/lanl2dz Geom=AllCheck Guess=TCheck SCF=Tight Pop=(Regular,NBORead) nosymm Int=UltraFine Density=Current

 $NBO bndidx $END

--link1--
%chk=Cu10pyrZ00.chk
#p b3lyp TD=(NSites=100)/lanl2dz Geom=AllCheck Guess=TCheck Pop=Regular nosymm

--link1--
%chk=Cu10pyrZ00.chk
#p  CIS=(NSites=100)/lanl2dz Geom=AllCheck Guess=TCheck Pop=Regular nosymm